Friday, October 30, 2009

Composition of Petroleum

An oil well produces predominantly crude oil, with some natural gas dissolved in it. So in common usage Petroleum includes both crude oil and natural gas. Whether crude oil or natural gas are predominantly a mixture of hydrocarbons. The lighter hydrocarbons methane, ethane, propane and butane, under surface pressure and temperature conditions, occur as gases, while the heavier ones from pentane and up are in the form of liquids or solids. Some of the gas come out of solution and be recovered as associated gas or solution gas, as the pressure is lower at the surface than underground. Some times gas recovered from gas well may contain heavier hydrocarbons such as pentane, hexane, and heptane in the gaseous state because of the higher underground temperature and pressure than that of the surface.

Under surface conditions these will condense out of the gas and form natural gas condensate, often shortened to condensate. Condensate resembles gasoline in appearance and is similar in composition to some volatile light crude oils.

The proportion of hydrocarbons in the petroleum mixture is highly variable between different oil fields and ranges from as much as 97% by weight in the lighter oils to as little as 50% in the heavier oils and bitumens.

The hydrocarbons in crude oil are mostly alkanes, cycloalkanes and various aromatic hydrocarbons while the other organic compounds contain nitrogen, oxygen and sulfur, and trace amounts of metals such as iron, nickel, copper and vanadium. The exact molecular composition varies widely from formation to formation but the proportion of chemical elements vary over fairly narrow limits as follows:


Composition by weight

Element

Percent range

Carbon

83 to 87%

Hydrogen

10 to 14%

Nitrogen

0.1 to 2%

Oxygen

0.1 to 1.5%

Sulfur

0.5 to 6%

Metals

less than 1000 ppm



Four different types of hydrocarbon molecules appear in crude oil. The relative percentage of each varies from oil to oil, determining the properties of each oil.


Composition by weight

Hydrocarbon

Average

Range

Paraffins

30%

15 to 60%

Naphthenes

49%

30 to 60%

Aromatics

15%

3 to 30%

Asphaltics

6%

remainder






Seismic Energy Dissipation Devices

Seismic Energy Dissipation Devices